The Blues scale (like most scales) has five fingerings which follow five basic chord shapes. These fingerings cover the entire fretboard when joined together. Following the low E form, the next fingering is the D form. (For further information about the five forms and how they relate to chord shapes see Progressive Blues Lead Guitar Method).
Try the following example which ascends the D form of the Blues scale.
Here is a lick using double stops in the D form. Practice it slowly at first.
Here is a complete 12 Bar Blues solo using the D form of the Blues scale.